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Functionalizaton of corroles: the nitration reaction

Authors :
Stefanelli, Manuela
Mastroianni, Marco
Nardis, Sara
Licoccia, Silvia
Fronczek, Frank R.
Smith, Kevin M.
Weihua Zhu
Zhongping Ou
Kadish, Karl M.
Paolesse, Roberto
Source :
Inorganic Chemistry. Dec 10, 2007, Vol. 46 Issue 25, 10791-10799
Publication Year :
2007

Abstract

The nitro-substituted silver(III) corrole obtained by reaction of corrole with AgN[O.sub.2] is studied using cyclic voltammetry and spectroelectrochemistry.The [pi]-cation radical of the complex acts as the reaction intermediate which is attacked by the nitrite ion.

Details

Language :
English
ISSN :
00201669
Volume :
46
Issue :
25
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.173077298