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Heterometallic cuboidal clusters [M.sub.3]M'[Q.sub.4](M=Mo, W; M'=Sn, Pb, As, Sb; Q=S, Se): from coordination compounds to supramolecular adducts

Authors :
Hernandez-Molina, Rita
Kalinina, Irina V.
Abramov, Pavel A.
Sokolov, Maxim N.
Virovets, Alexandr V.
Platas, Javier G.
Llusar, Rosa
Polo, Victor
Vicent, Cristian
Fedin, Vladimir P.
Source :
Inorganic Chemistry. Jan 7, 2008, Vol. 47 Issue 1, 306-314
Publication Year :
2008

Abstract

Incomplete cuboidal clusters when reacted with group 14 and 15 metal complexes with [s.sup.2][p.sup.0] electronic configuration resulted in the formation of heterometal incorporated cuboidal clusters. X-ray diffraction studies showed the cuboidal clusters as weak complexes of the cluster tridentate ligand with [EX.sub.3].

Details

Language :
English
ISSN :
00201669
Volume :
47
Issue :
1
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.173736491