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Half-sandwich structure of cyclopentadienyl dialuminum ([Al.sub.2]([n.sup.5]-[C.sub.5][H.sub.5]) from pulsed-field ionization electron spectroscopy and ab initio calculations

Half-sandwich structure of cyclopentadienyl dialuminum ([Al.sub.2]([n.sup.5]-[C.sub.5][H.sub.5]) from pulsed-field ionization electron spectroscopy and ab initio calculations

Authors :
Yuxiu Lei
Dong-Sheng Yang
Source :
Journal of Physical Chemistry A. Feb 21, 2008, Vol. 112 Issue 7, p1430, 6 p.
Publication Year :
2008

Abstract

Cyclopentadienyl dialuminum with a half sandwich structure is prepared in a pulsed laser ablation cluster beam source and identified with a time of flight photoionization mass spectrometer. The high resolution electron spectrum of this complex is obtained using pulsed field ionization zero electron kinetic energy photoelectron spectroscopy.

Details

Language :
English
ISSN :
10895639
Volume :
112
Issue :
7
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.177050613