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Conjugation and hyperconjugation in conformational analysis of cyclohexene derivatives containing an exocyclic double bond

Authors :
Shishkina, Svetlana V.
Shishkin, Oleg V.
Desenko, Sergey M.
Leszczynski, Jerzy
Source :
Journal of Physical Chemistry A. July 31, 2008, Vol. 112 Issue 30, 7080-7089
Publication Year :
2008

Abstract

The equilibrium geometry, as well as the conjugation and hyperconjugation occurring in the conformational analysis of the cyclohexene derivatives containing an exocyclic double bond are explained. The equilibrium conformation of the ring present in the system is shown to be highly dependent on the conjugation taking place between the endocyclic and exocyclic double bonds.

Details

Language :
English
ISSN :
10895639
Volume :
112
Issue :
30
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.183881743