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First row transition metal ion-assisted ammonia-borane hydrolysis for hydrogen generation
- Source :
- Inorganic Chemistry. August 18, 2008, Vol. 47 Issue 16, 7424-7429
- Publication Year :
- 2008
-
Abstract
- The catalytically active species formed in the reaction of the first row transition metal ions such as [Co.sup.2+], [Ni.sup.2+], and [Cu.sup.2+] with ammonia-borane hydrolyze ammonia-borane to generate hydrogen are described. The results obtained demonstrated the deployment of stable first row transition metal catalysts for the generation of [H.sub.2] from AB via hydrolysis.
- Subjects :
- Borane -- Chemical properties
Borane -- Structure
Nickel compounds -- Chemical properties
Nickel compounds -- Structure
Ammonium chloride -- Chemical properties
Ammonium chloride -- Structure
Ammonium compounds -- Chemical properties
Ammonium compounds -- Structure
Ammonium paratungstate -- Chemical properties
Ammonium paratungstate -- Structure
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 47
- Issue :
- 16
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.185190567