Back to Search Start Over

The mechanism responsible for extraordinary Cs ion selectivity in crystalline silicotitanate

Authors :
Celestian, Aaron J.
Kubicki, James D.
Hanson, Jonathon
Clearfield, Abraham
Parise, John B.
Source :
Journal of the American Chemical Society. Sept 3, 2008, Vol. 130 Issue 35, 11689-11694
Publication Year :
2008

Abstract

Time-resolved X-ray and neutron scattering with theoretical calculations have shown a mechanism whereby hydrogen crystalline silicotitanate (H-CST) has achieved its remarkable ion-exchange selectivity for cesium. The studies have shown that the interactions have induced a subtle conformational rearrangement in CST that unlocks the preferred Cs site and increases the overall capacity and selectivity for ion exchange.

Details

Language :
English
ISSN :
00027863
Volume :
130
Issue :
35
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.185407452