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Synthesis, characterization, and electrochemistry of sigma-bonded cobalt corroles in high oxidation states
- Source :
- Inorganic Chemistry. Sept 11, 1996, Vol. 35 Issue 19, p5577, 7 p.
- Publication Year :
- 1996
-
Abstract
- Two high-valent phenyl sigma-bonded cobalt corroles in +IV and +V oxidation states are synthesized and analyzed by electrochemistry, spectroscopy and structural characterization. The compounds are represented as (OEC)Co(C6H5) and ((OEC)Co(C6H5))ClO4, in which OEC is the trianion of 2,3,7,8,12,13,17,18-octaethylcorrole. The former is a novel example of the only isolated tetrapyrrole complex that has a strong cobalt(IV) property. It exhibits three reversible one-electron transfers in PhCN containing 0.2 M TBAP.
- Subjects :
- Cobalt -- Research
Electrochemistry -- Research
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 35
- Issue :
- 19
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.18801578