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Oxo-ester mediated native chemical ligation: concept and applications

Authors :
Qian Wan
Jin Chen
Yu Yuan
Danishefsky, Samuel J.
Source :
Journal of the American Chemical Society. Nov 26, 2008, Vol. 130 Issue 47, 15814-15816
Publication Year :
2008

Abstract

A major simplification is described in the field of native chemical ligation (NCL). The feasibility of NCL with oxo- rather than thioesters is demonstrated by balancing acyl donor potential with substrate stability.

Details

Language :
English
ISSN :
00027863
Volume :
130
Issue :
47
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.192539013