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Stereospecific alkane hydroxylation with H2O2 catalyzed by an iron(II)-tris(2-pyridylmethyl)amine complex
- Source :
- Journal of the American Chemical Society. June 25, 1997, Vol. 119 Issue 25, p5964, 2 p.
- Publication Year :
- 1997
-
Abstract
- The details of the stereospecific alkane hydroxylation with H2O2 catalyzed by an iron(II)-tris(2-pyridylmethyl)amine complex was described. Data indicated that iron(II)-tris(2-pyridylmethyl)amine complex/H2O2 behaved differently from [Fe2O(TPA)2(H2O)2]4+/tBuOOH. The resemblance in reactivity of the title compound to heme catalysts indicated that similar mechanisms may apply to both types of catalysts.
- Subjects :
- Hydroxylation -- Analysis
Alkanes -- Analysis
Chemistry
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 119
- Issue :
- 25
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20008727