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Enhancement of a catalysis-based fluorometric detection method for palladium through rational fine-tuning of the palladium species
- Source :
- Journal of the American Chemical Society. April 15, 2009, Vol. 131 Issue 14, 5163-5171
- Publication Year :
- 2009
-
Abstract
- The improvement of the catalysis-based fluorescent probe for palladium is described by rationally fine-tuning the redox and coordination chemistries of the palladium species involved in the O-deallylation reaction. The studies have shown palladium detection in various active pharmaceutical ingredients, spent catalytic converter materials and a metal scavenger resin.
- Subjects :
- Allylic compounds -- Structure
Allylic compounds -- Chemical properties
Catalysis -- Analysis
Coordination compounds -- Structure
Coordination compounds -- Chemical properties
Oxidation-reduction reaction -- Analysis
Palladium -- Chemical properties
Palladium -- Optical properties
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 131
- Issue :
- 14
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.200818248