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Magnetic anisotropy of dysprosium(III) in a low-symmetry environment: a theoretical and experimental investigation

Authors :
Bernot, Kevin
Luzon, Javier
Bogani, Lapo
Etienne, Mael
Sagregorio, Claudio
Shanmugam, Muralidharan
Caneschi, Andrea
Sessoli, Roberta
Gatteschi, Dante
Source :
Journal of the American Chemical Society. April 22, 2009, Vol. 131 Issue 15, 5573-5579
Publication Year :
2009

Abstract

A mixed theoretical and experimental approach is used for determining the local magnetic anisotropy of the dysprosium(III) ion in a low-symmetry environment. The analysis of the temperature and field dependence of the magnetization has shown that the Dy ion has transmitted an antiferromagnetic interaction between radicals but that the Dy-radical interaction is ferromagnetic.

Details

Language :
English
ISSN :
00027863
Volume :
131
Issue :
15
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.200888665