Back to Search Start Over

Synthesis and chemistry of CF3C6F4OC6F4 group 14/16 derivatives

Authors :
Krumm, Burkhard
Kirchmeier, Robert L.
Shreeve, Jean'ne M.
Source :
Inorganic Chemistry. Nov 5, 1997, Vol. 36 Issue 23, p5222, 9 p.
Publication Year :
1997

Abstract

There is a clear reaction of CF3C6F4OC6F4Li5 generated in situ with group 16 elements (S, Se, Te) to form CF3C6F4OC6F4SH (CF3C6F4OC6F4Se)2 and (CF3C6F4OC6F3Te)2/(CF3C6F4OC6F3)2Te. It is possible to react B(OMe)3/H2o27 with CF3C6F4OC6F4Li to obtain the synthesis of CF3C6F4OC6F4OH. Hydrolysis and recovery of the precursor CF3C6F4OC6F4H5 results from the exposure of CF3C6F4OC6F4Li to the atmosphere. The selenophenol CF3C6F4OC6F4SeH that must be created initially in the reaction with selenium is not isolable.

Details

ISSN :
00201669
Volume :
36
Issue :
23
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.20119864