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Synthesis and characterization of a series of monometallo-, bimetallo-, and heterobimetallo-1,2-ethene-linked cofacial bisporphyrins
- Source :
- Inorganic Chemistry. March 23, 1998, Vol. 37 Issue 6, p1150, 11 p.
- Publication Year :
- 1998
-
Abstract
- The synthesis and characterization of a series of monometallo-, bimetallo-, and heterobimetallo-1,2-ethene-linked cofacial bisporphyrins are presented. Two heterobimetallic cofacial bisporphyrins were synthesized easily by initially forming monometalated species with subsequent insertion of a second metal ion. Initial monometalations were observed to be slower under dilute conditions in CH2Cl2/MeOH at refluc but under dilute conditions in hot DMF, the insertion rate was sufficiently fast to enable isolation of the monometalated cofacial isomers as the major product.
- Subjects :
- Porphyrins -- Research
Oxidation-reduction reaction -- Research
Chemistry
Subjects
Details
- ISSN :
- 00201669
- Volume :
- 37
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.20749279