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Substituent-induced perturbation symmetries and distortions of meso-tert-butylporphyrins
- Source :
- Inorganic Chemistry. May 4, 1998, Vol. 37 Issue 9, p2117, 12 p.
- Publication Year :
- 1998
-
Abstract
- A study was conducted to examine the effects of the symmetry of substitution pattern and substituent orientations on the out-plane and in-plane distortions of the macrocyle of nickel porphyrins. These nickel porphyrins were analyzed through the use of molecular mechanics calculations, X-ray crystallography, UV visible absorption spectroscopy and resonance Raman spectroscopy. Results revealed that out-plane and in-plane distortions were dependent on perturbation symmetry of the peripheral substituents.
Details
- ISSN :
- 00201669
- Volume :
- 37
- Issue :
- 9
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.21010464