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New type of Li ion conductor with 3D interconnected nanopores via polymerization of a liquid organic electrolyte-filled lyotropic liquid-crystal assembly

Authors :
Kerr, Robert L.
Miller, Seth A.
Shoemaker, Richard K.
Elliott, Brian J.
Gin, Douglas L.
Source :
Journal of the American Chemical Society. Nov 11, 2009, Vol. 131 Issue 44, 15972-15973
Publication Year :
2009

Abstract

The development of a new type of polymer electrolyte material for Li ion transport based on a polymerizable lyotropic liquid crystal that forms a type-II bicontinuous cubic ([Q.sub.II]) phase is reported. Preliminary variable-temperature ion conductivity and NMR DOSY studies showed that liquidlike diffusion is present in the [Q.sub.II] nanochannels and that good ion conductivity and PC mobility are retained down to 35 degree [Celsius].

Details

Language :
English
ISSN :
00027863
Volume :
131
Issue :
44
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.213539254