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Synthesis of an acyltrifluoroborate and its fusion with azides to form amides

Authors :
Molander, Gary A.
Raushel, Jessica
Ellis, Noel M.
Source :
Journal of Organic Chemistry. June 18, 2010, Vol. 75 Issue 12, 4304-4306
Publication Year :
2010

Abstract

A uniquely stable acyl potassium trifluoroborate, potassium (2-phenylacetyl)trifluoroborate, is prepared and isolated. The reagent has reacted with azides to form amides in the presence of an activating Lewis acid.

Details

Language :
English
ISSN :
00223263
Volume :
75
Issue :
12
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.231951480