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Enantioselective nickel-catalyzed reductive coupling of alkynes and imines

Authors :
Chang-Yue Zhou
Shou-Fei Zhu
Li-Xin Wang
Qi-Lin Zhou
Source :
Journal of the American Chemical Society. August 18, 2010, Vol. 132 Issue 32, 10955-10957
Publication Year :
2010

Abstract

The article presents a new approach for the enantioselective nickel-catalyzed reductive coupling that can be employed to various alkynes and imines. The application of a nickel catalyst with chiral spiro phosphine ligand for the induction of different chirals is also analyzed.

Subjects

Subjects :
Nickel -- Chemical properties
Oxidation-reduction reaction -- Analysis
Schiff bases -- Chemical properties
Catalysis -- Analysis
Chemistry

Details

Language :
English
ISSN :
00027863
Volume :
132
Issue :
32
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.237765488

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