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Racemization free protocol for the synthesis of N-tert-butanesulfinyl ketimines

Authors :
Datta, Gopal K.
Ellman, Jonathan A.
Source :
Journal of Organic Chemistry. Sept 17, 2010, Vol. 75 Issue 18, 6283-6285
Publication Year :
2010

Abstract

A general and robust racemization-free protocol is described for preparing a variety of N-tert-butanesulfinyl ketimines. The reaction progress is monitored by [super 1]H NMR by using the nonperturbing internal standard diglyme and ketimines are formed in either THF or CPME (cyclopentyl methyl ether) as solvent with heating to reflux.

Details

Language :
English
ISSN :
00223263
Volume :
75
Issue :
18
Database :
Gale General OneFile
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.238531181