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Controlled orientation of polyconjugated guest molecules in tunable host cavities
- Source :
- Journal of the American Chemical Society. Oct 20, 2010, Vol. 132 Issue 41, 14603-14616
- Publication Year :
- 2010
-
Abstract
- Linear conjugated guest molecules with high aspect ratios have formed inclusion compounds with guanidinium organodisulfonate (GDS) host frameworks in which organodisulfonate ' pillars' have connected opposing GS sheets to generate lamellar architectures that reflect templating by the guest. The effects of the different framework architectures and packing motifs are marked as bathochromic shifts in the absorption and emission spectra of the guest when compared with their spectra in methanol solutions.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 132
- Issue :
- 41
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.241904462