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[m x n] metal ion arrays templated by coordination cages
- Source :
- Journal of the American Chemical Society. Nov 10, 2010, Vol. 132 Issue 44, 15553-15555
- Publication Year :
- 2010
-
Abstract
- Three-dimensional m * n arrays of metal ion clusters, assembled as aromatic stacks of planar polynuclear metal complexes within columnar coordination cages are described. The reactions between hexanuclear [Au.sub.3]-[Au.sub.3] clusters and Ag(I) ions to prepare a silver-sandwiched hetero-[Au.sub.3]-Ag-[Au.sub.3] cluster are described.
- Subjects :
- Gold -- Chemical properties
Gold -- Electric properties
Organometallic compounds -- Structure
Organometallic compounds -- Chemical properties
Organometallic compounds -- Electric properties
Silver -- Chemical properties
Silver -- Electric properties
X-ray crystallography -- Usage
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 132
- Issue :
- 44
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.244916317