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[m x n] metal ion arrays templated by coordination cages

Authors :
Osuga, Takafumi
Murase, Takashi
Ono, Kosuke
Yamauchi, Yoshihiro
Fujita, Makoto
Source :
Journal of the American Chemical Society. Nov 10, 2010, Vol. 132 Issue 44, 15553-15555
Publication Year :
2010

Abstract

Three-dimensional m * n arrays of metal ion clusters, assembled as aromatic stacks of planar polynuclear metal complexes within columnar coordination cages are described. The reactions between hexanuclear [Au.sub.3]-[Au.sub.3] clusters and Ag(I) ions to prepare a silver-sandwiched hetero-[Au.sub.3]-Ag-[Au.sub.3] cluster are described.

Details

Language :
English
ISSN :
00027863
Volume :
132
Issue :
44
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.244916317