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Scope and limitations of cyclopropanations with sulfur ylides

Authors :
Appel, Roland
Mayr, Herbert
Hartmann, Nicolai
Source :
Journal of the American Chemical Society. Dec 22, 2010, Vol. 132 Issue 50, 17894-17900
Publication Year :
2010

Abstract

The UV-vis spectroscopy technique is employed to explain the mechanisms involved in the reactions of stabilized and semistabilized sulfur ylides with benzhydrylium ions. The various advantages and issues related to the application of sulfur ylides for the purpose of cyclopropanations are explained.

Subjects

Subjects :
Cyclopropane compounds -- Structure
Cyclopropane compounds -- Chemical properties
Organosulfur compounds -- Structure
Organosulfur compounds -- Chemical properties
Ultraviolet spectroscopy -- Usage
Chemistry

Details

Language :
English
ISSN :
00027863
Volume :
132
Issue :
50
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.249632254

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