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Reactions of O(3P) with alkenes: H, CH2CHO, CO, and OH channels

Authors :
Quandt, Robert
Min, Zhiyuan
Wang, Xuebin
Bersohn, Richard
Source :
Journal of Physical Chemistry A. Jan 1, 1998, Vol. 102 Issue 1, p60, 5 p.
Publication Year :
1998

Abstract

Research was conducted to examine the H, CH2CHO, CO and OH products of the reaction of O(3P) atom with alkenes using laser-induced fluorescence under single-collision conditions. Near room temperature Boltzmann distributions were used to characterize the CO and OH rotational state populations. Results indicate that chemical reactions that do not involve the sie chains such as release of H atoms or breakup of HCO depend sensitively on the length of the chains.

Details

ISSN :
10895639
Volume :
102
Issue :
1
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.54005390