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Evidence for an unusual MO diagram

Authors :
Collman, James P.
Harford, S.T.
Franzen, Stefan
Marchon, Jean-Claude
Maldivi, Pascale
Shreve, Andrew P.
Woodruff, William H.
Source :
Inorganic Chemistry. May 3, 1999, Vol. 38 Issue 9, p2085, 8 p.
Publication Year :
1999

Abstract

Research was conducted to examine various spectroscopic studies of WOs and MoRu porphyrin dimers using variable-temperature 1H NMR, resonance Raman, magnetic susceptibility and X-ray crystallography. The objective was to determine a proper molecular orbital diagram for the dimers. Results demonstrate an unusual molecular orbital diagram which has never been observed before in metal-metal bonded metalloporphyrin dimers.

Details

ISSN :
00201669
Volume :
38
Issue :
9
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.54774579