Relationship between the dipole strength of ligand pre-edge transitions and metal - ligand covalency

Authors :: Neese, Frank
Hedman, Britt
Hodgson, Keith O.
Solomon, Edward I.
Source :: Inorganic Chemistry. Oct 18, 1999, Vol. 38 Issue 21, p4854, 7 p.
Publication Year :: 1999
Abstract: The article presents analysis of electric dipole contributions to pre-edge intensities in ligand K-edge X-ray absorption spectra based on metal-ligand covalent-bonding contributions for a prototype system. Identification of one- and two-center contributions to the intensity is presented.

Subjects :: Chemistry, Inorganic -- Research
Ligands -- Research
Metals -- Physiological aspects
Valence -- Analysis
Chemistry

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