Kinetic and thermodynamic studies of reaction of radicalCr(CO) (sub)3 C (sub)5 Me (sub)5, HCr(CO) (sub)3 C (sub)5 Me (sub)5, and PhSCr(CO) (sub)3 C (sub)5 Me (sub)5 with radicalNO. Reductive elimination of thermodynamically unstable molecules HNO and RSNO driven by formation of the strong Cr-NO bond

Research has been conducted on the reaction of H-Cr(CO) (sub)3 C (sub)5 Me (sub)5 with radicalNO. Decomposition of the initial product HNO has been described.