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Palladium-catalyzed reactions of allenes

Authors :
Zimmer, Reinhold
Dinesh, Chimmanamada U.
Nandanan, Erathodiyil
Khan, Faiz Ahmed
Source :
Chemical Reviews. August, 2000, Vol. 100 Issue 8, p3067, 59 p.
Publication Year :
2000

Abstract

The role of pi-allylpalladium intermediate in the organic synthesis is central to the palladium-catalyzed reactions of allenes with carbon and heteroatom nucleophiles. The application and reactivity of the pi-allylpalladium species in the synthesis of natural products using allenes and mechanistic aspects of reactions involved are discussed.

Details

ISSN :
00092665
Volume :
100
Issue :
8
Database :
Gale General OneFile
Journal :
Chemical Reviews
Publication Type :
Academic Journal
Accession number :
edsgcl.66925552