Elastic composites fabricating for electromagnetic interference shielding based on MWCNTs and [Fe.sub.3][O.sub.4] unique distribution in immiscible NR/NBR blends

Electromagnetic interference (EMI) shielding rubber nanocomposites were fabricated via a simple rubber roll milling technique based on the filler distribution behavior in the immiscible natural rubber (NR) and acrylonitrile-butadiene (NBR) (50/50) blends with varying amounts of multiwall carbon nano tubes and [Fe.sub.3][O.sub.4] nanoparticles. All nanocomposites showed a co-continuous phase structure, while the distribution behavior of filler was diverse correlated with the filler content and type. The mechanical properties, electrical conductivity, and EMI shielding effectiveness (SE) of rubber composites were characterized. The maximum EMI SE of 29.4 dB at 12.4 GHz was achieved in the rubber composites loaded with 15 phr MWCNTs and 15 phr [Fe.sub.3][O.sub.4] nanoparticles. The EMI shielding mechanisms of such materials were also discussed. The observation in this work provided a possible idea to the industrial manufacture electromagnetic interference shielding rubber nanocomposites, and contributed to expanding its application fields with higher mechanical property requirements and flexibility. KEYWORDS electromagnetic interference shielding, immiscible rubber blend, mechanical properties, polymer-matrix composites
1 | INTRODUCTION With extensive applications of electronic and telecommunication devices in daily life, electromagnetic pollution has become one of the serious environmental problems because of its adverse effects on [...]