Chemo- and diastereoselectivity in the dimethyldioxirane oxidation of 2,3-dihydro-4H-1-benzothiopyran-4-ones and 4H-1-benzothiopyran-4-ones. Unusual reactivity of 4H-1-benzothiopyran-4-one 1-oxides

Authors :: Patonay, Tamas
Adam, Waldemar
Levai, Albert
Kover, Peter
Nemeth, Marta
Peters, Eva-Maria
Peters, Karl
Source :: Journal of Organic Chemistry. April 6, 2001, Vol. 66 Issue 7, p2275, 6 p.
Publication Year :: 2001
Abstract: Research has been conducted on hiochromanone- and thiochromone-type substrates' dioxirane oxidation. The chemoselectivity and diastereselectivity of oxygen transfer have been investigated.

Subjects :: Chemistry, Organic -- Research
Oxidation-reduction reaction -- Physiological aspects
Oxides -- Research
Oxygen -- Physiological aspects
Sulfones -- Physiological aspects
Biological sciences
Chemistry

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