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Aerobic oxidation of N-alkylamides catalyzed by N-hydroxyphthalimide under mild conditions. Polar and enthalpic effects
- Source :
- Journal of Organic Chemistry. April 19, 2002, Vol. 67 Issue 8, p2671, 6 p.
- Publication Year :
- 2002
-
Abstract
- Research has been conducted on N-hydroxyphthalimide which is combined with cobalt salts. The oxidation of N-alkylamides by O (sub)2 catalyzed by N-hydroxyphthalimide has been examined and the results indicate that this oxidation allows alkylamine reverse transformation to carbonyl compounds via intermediate amides.
- Subjects :
- Chemistry, Organic -- Research
Oxidation-reduction reaction -- Physiological aspects
Amides -- Physiological aspects
Enthalpy -- Research
Amines -- Physiological aspects
Carbonyl compounds -- Physiological aspects
Cobalt -- Physiological aspects
Salts -- Physiological aspects
Biological sciences
Chemistry
Subjects
Details
- ISSN :
- 00223263
- Volume :
- 67
- Issue :
- 8
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.86172616