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Reactivities of methylenetriangulanes and spirocyclopropanated bicyclopropylidenes toward bromine. Relative stabilities of spirocyclopropanated versus methyl-substituted bromonium ions
- Source :
- Journal of Organic Chemistry. June 14, 2002, Vol. 67 Issue 12, p4100, 15 p.
- Publication Year :
- 2002
-
Abstract
- Research has been conducted on the methylenecyclopropane, bicyclopropylidene and spirocyclopropanated methylenecyclopropanes. The bromine additions to these compound carried out in methanol have been investigated and the results indicate the enhanced bromination rate with the increased number of spiroannelated three-membered rings.
- Subjects :
- Chemistry, Organic -- Research
Reactivity (Chemistry) -- Research
Bromine -- Physiological aspects
Ions -- Physiological aspects
Substitution reactions -- Physiological aspects
Cyclic compounds -- Physiological aspects
Ring formation (Chemistry) -- Physiological aspects
Methanol -- Physiological aspects
Biological sciences
Chemistry
Subjects
Details
- ISSN :
- 00223263
- Volume :
- 67
- Issue :
- 12
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.89263408