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Stabilization of the P(CF (sub)3) (sub)2 (super)- ion as a reversible CS (sub)2 adduct, [P(CF (sub)3) (sub)2 CS (sub)2] (super)-, and its potential use as a nucleophilic P(CF (sub)3) (sub)2 (super)- source: synthesis and structure of [18-crown-6-K][P(C (sub)6 F (sub)5) (sub)2 CS (sub)2]

Authors :
Hoge, Berthold
Thosen, Christoph
Herrmann, Tobias
Pantenburg, Ingo
Source :
Inorganic Chemistry. April 22, 2002, Vol. 41 Issue 8, p2260, 6 p.
Publication Year :
2002

Abstract

Research has been conducted on the P(CF (sub)3) (sub)2 (super)- ion. The ability of this ion to stabilize in solution has been investigated and the results indicate that this feature can affect the ion's capability to be used in nucleophilic displacement reactions.

Details

ISSN :
00201669
Volume :
41
Issue :
8
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.94197448