Nanomagnetic Control of Intersystem Crossing

Authors :: Cohen, Adam Ezra
Source :: Cohen, Adam E. 2009. Nanomagnetic control of intersystem crossing. The Journal of Physical Chemistry A 113(41): 11084-11092.
Publication Year :: 2009
Publisher :: American Chemical Society, 2009.
Abstract: A theory is presented for how magnetic nanostructures can catalyze intersystem crossing in molecular radical pairs. Magnetic field gradients near physically realistic nanostructures are strong enough to induce a relative reorientation of two electronic spins in <1 ns, overwhelming nuclear hyperfine coupling as a driver of intersystem crossing. Nanomagnetic control of intersystem crossing represents a form of heterogeneous catalysis that does not require molecular contact, but only short-range magnetic coupling.<br />Chemistry and Chemical Biology<br />Physics

Language :: English
ISSN :: 10895639
Database :: Digital Access to Scholarship at Harvard (DASH)
Journal :: Cohen, Adam E. 2009. Nanomagnetic control of intersystem crossing. The Journal of Physical Chemistry A 113(41): 11084-11092.
Publication Type :: Academic Journal
Accession number :: edshld.1.4699752
Document Type :: Journal Article
Full Text :: https://doi.org/10.1021/jp907113p