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Probing Lewis Acid-Base Interactions in Single-Molecule Junctions

Authors :
Liu, Xunshan
Li, Xiaohui
Sangtarash, Sara
Sadeghi, Hatef
Decurtins, Silvio
Häner, Robert
Hong, Wenjing
Lambert, Colin
Liu, Shi-xia
Liu, Xunshan
Li, Xiaohui
Sangtarash, Sara
Sadeghi, Hatef
Decurtins, Silvio
Häner, Robert
Hong, Wenjing
Lambert, Colin
Liu, Shi-xia
Publication Year :
2018

Abstract

A novel strategy to regulate the tunneling mechanism for charge transport through an organoborane wire via Lewis acid-base interactions has been developed. A change from LUMO- to HOMO-dominated charge transport upon the addition of the fluoride is verified both experimentally and theoretically.

Details

Database :
OAIster
Notes :
Liu, Xunshan and Li, Xiaohui and Sangtarash, Sara and Sadeghi, Hatef and Decurtins, Silvio and Häner, Robert and Hong, Wenjing and Lambert, Colin and Liu, Shi-xia (2018) Probing Lewis Acid-Base Interactions in Single-Molecule Junctions. Nanoscale, 10 (38). pp. 18131-18134. ISSN 2040-3364
Publication Type :
Electronic Resource
Accession number :
edsoai.on1057892686
Document Type :
Electronic Resource