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Structure of sanguinarine base

Authors :
UCL
Dostal, J.
Bochorakova, H
Taborska, E.
Slavik, J.
Potacek, M.
Budesinsky, M
de Hoffmann, Edmond
UCL
Dostal, J.
Bochorakova, H
Taborska, E.
Slavik, J.
Potacek, M.
Budesinsky, M
de Hoffmann, Edmond
Source :
Journal of Natural Products, Vol. 59, no. 6, p. 599-602 (1996)
Publication Year :
1996

Abstract

The structure of sanguinarine free base was examined. The base is either bis[6-(5,6-dihydrosanguinarinyl)] ether (3) or bis[6-(5,6-dihydrosanguinarinyl)]amine (4) depending on whether Na2CO3 or NH3, respectively, is used as an alkalizing agent. Oxysanguinarine (5) was identified as a side product formed by disproportionation of the pseudobase intermediate 2a.

Details

Database :
OAIster
Journal :
Journal of Natural Products, Vol. 59, no. 6, p. 599-602 (1996)
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1130561381
Document Type :
Electronic Resource