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A convenient and versatile preparation of unsymmetrical bis-metallic isobutene derivatives

Authors :
UCL - Cliniques universitaires Saint-Luc
UCL - MD/FARM - Ecole de pharmacie
Driesschaert, Benoît
Leroy, Bernard
UCL - Cliniques universitaires Saint-Luc
UCL - MD/FARM - Ecole de pharmacie
Driesschaert, Benoît
Leroy, Bernard
Source :
Synlett : accounts and rapid communications in synthetic organic chemistry, , no. 13, p. 2148-2150 (2006)
Publication Year :
2006

Abstract

Synthetically useful unsymmetrical bis-silyl or silylstannyl isobutene derivatives are conveniently prepared from selenoisobutene 5, a versatile equivalent of the isobutene dianion. Sequential treatment of this selenated compound with n-butyl-lithium and the required chlorosilanes or chlorostannanes leads efficiently to the corresponding functionalized isobutenes.

Details

Database :
OAIster
Journal :
Synlett : accounts and rapid communications in synthetic organic chemistry, , no. 13, p. 2148-2150 (2006)
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1130567786
Document Type :
Electronic Resource