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Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions

Authors :
Li, Man-Bo
Yang, Ying
Rafi, Abdolrahim A.
Oschmann, Michael
Svensson Grape, Erik
Inge, A. Ken
Córdova, Armando
Bäckvall, Jan-E.
Li, Man-Bo
Yang, Ying
Rafi, Abdolrahim A.
Oschmann, Michael
Svensson Grape, Erik
Inge, A. Ken
Córdova, Armando
Bäckvall, Jan-E.
Publication Year :
2020

Abstract

A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active Pd-II, which results in high efficiency of the heterogeneous catalytic system.

Details

Database :
OAIster
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1235040988
Document Type :
Electronic Resource
Full Text :
https://doi.org/10.1002.anie.202001809