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Direct template synthesis of a heterometallic Co-III/Zn-II complex : The advantage of using a metal powder as a starting material

Authors :
Shevchenko, Denys V.
Kokozay, Vladimir N.
Krasovska, Marina V.
Shishkin, Oleg V.
Shevchenko, Denys V.
Kokozay, Vladimir N.
Krasovska, Marina V.
Shishkin, Oleg V.
Publication Year :
2008

Abstract

The heterometallic complex [Co(L-1)Cl-2][ZnCl3(DMF)] (L-1 = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-ene) has been obtained by direct template synthesis from cobalt powder, zinc oxide, zinc chloride, ethylenediamine dihydrochloride and acetone in dimethylformamide and characterized by X-ray crystallographic analysis. The mechanism of the complex formation is suggested.

Details

Database :
OAIster
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1235164665
Document Type :
Electronic Resource
Full Text :
https://doi.org/10.1016.j.inoche.2008.07.013