40Ar/39Ar chronological constraints on syn- and post-Variscan biotite porphyroblasts from the Iberian Chains, NE Spain

We perform a multidisciplinary study of biotite porphyroblasts and veinlet infills hosted in Cambrian strata of the hanging walls from the NW-SE-trending Datos, Jarque and Daroca thrusts (Iberian Chains). Stratigraphic and microstructural crosscutting features indicate that a biotite isograd runs parallel to the southeastern transects of the three thrusts. The metamorphic grade reached in the southeastern edge of the Iberian Chains is clearly distinct from both the Cadomian epizonal metamorphism, exclusively recorded in the Ediacaran–basal Cambrian Paracuellos Group, and the Variscan anchizone metamorphism recorded throughout Cambrian–Devonian strata. During post–Variscan negative inversion tectonics, renewed K-metasomatism along the same thrusts led to crystallisation of geochemically similar biotites in parallel fissures and veins. 40Ar/39Ar ages are (i) latest Westphalian–to–Guadalupian (285.82 ± 23.75 Ma) for metamorphic biotite porphyroblasts affected by diffusion loss of Ar, including the Carboniferous–Permian transition within error; and (ii) Early Triassic (246.87 ± 5.36 Ma) for biotite occlusion in post–Variscan veinlets. The Iberian Chains represent the southeastern prolongation of the Cantabrian and West Asturian-Leonese zones. The latter displays a uniform eastward decrease in metamorphic grade, whereas the Iberian Chains exhibits a heterogeneous distribution of low-grade metamorphic conditions (chlorite zone). The local presence of the biotite isograd is linked to the higher tectonic gradients associated with the Daroca, Jarque and Datos thrusts, quite similar to the metamorphic isogrades recognized both in the northeastern edge of the Demanda Massif and the Novellana-Pola de Allande-Degaña Belt of the West Asturian-Leonese Zone. This distribution allows the identification of a broad NW-SE belt of biotite-in isograd-related synkinematic metamorphism, following the western contact of the Narcea Antiform, the Anguiano Thrust and the southeastern edges of