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The lowest singlet and triplet states of the oxyallyl diradical

Authors :
Ichino, Takatoshi
Villano, Stephanie
Gianola, Adam
Goebbert, Daniel
Velarde, Luis
Sanov, Andrei
Blanksby, Stephen
Zhou, X.
Hrovat, David
Borden, Weston
Lineberger, W
Ichino, Takatoshi
Villano, Stephanie
Gianola, Adam
Goebbert, Daniel
Velarde, Luis
Sanov, Andrei
Blanksby, Stephen
Zhou, X.
Hrovat, David
Borden, Weston
Lineberger, W
Source :
Angewandte Chemie (International Edition)
Publication Year :
2009

Abstract

Small S-T splitting : The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

Details

Database :
OAIster
Journal :
Angewandte Chemie (International Edition)
Notes :
application/pdf
Publication Type :
Electronic Resource
Accession number :
edsoai.on1287977384
Document Type :
Electronic Resource