Astronomical calibration of Ar-40/Ar-39 reference minerals using high-precision, multi-collector (ARGUSVI) mass spectrometry

The new generation of multi-collector mass spectrometers (e.g. ARGUSVI) permit ultra-high precision (<0.1%) Ar-40/Ar-39 geochronology of rocks and minerals. At the same time, the Ar-40/Ar-39 method is limited by relatively large uncertainties (>1%) in K-40 decay constants and the ages of natural reference minerals that form the basis of the technique. For example, reported ages for widely used Ar-40/Ar-39 reference materials, such as the ca. 28 Ma Fish Canyon Tuff sanidine (FCTs) and the ca. 1.2 Ma Alder Creek Rhyolite sanidine (ACRs), vary by >1%. Recent attempts to independently calibrate these reference minerals have focused on K-Ar analyses of the same minerals and inter-comparisons with astronomically tuned tephras in sedimentary sequences and U-Pb zircon ages from volcanic rocks. Most of these studies used older generation (effectively single-collector) mass spectrometers that employed peak-jumping analytical methods to acquire Ar-40/Ar-39 data. In this study, we reassess the inter-calibration and ages of commonly used Ar-40/Ar-39 reference minerals Fish Canyon Tuff sanidine (FCTs), Alder Creek Rhyolite sanidine (ACRs) and Mount Dromedary biotite (MD2b; equivalent to GA-1550 biotite), relative to the astronomically tuned age of A1 Tephra sanidine (A1Ts), Faneromeni section, Crete (Rivera et al., 2011), using a multi-collector ARGUSVI mass spectrometer. These analyses confirm the exceptional precision capability (<0.1%) of this system, compared to most previous studies. All sanidine samples (FCTs, ACRs and A1Ts) exhibit discordant Ar-40/Ar-39 step-heating spectra, with generally monotonically increasing ages (similar to 1% gradients). The similarity in these patterns, mass-dependent fractionation modeling, and results from step-crushing experiments on FCTs, which yield younger apparent ages, suggest that the discordance may be due to a combination of recoil loss and redistribution of (ArK)-Ar-39 and isotope mass fractionation. In contrast to our previous infere