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Stereochemistry of electrophilic attack at 34e(-) dimetallic complexes: the case of diiron dithiolato carbonyls plus MeS+

Authors :
Olsen, M
Gray, D
Rauchfuss, T
DE GIOIA, L
Zampella, G
DE GIOIA, LUCA
ZAMPELLA, GIUSEPPE
Olsen, M
Gray, D
Rauchfuss, T
DE GIOIA, L
Zampella, G
DE GIOIA, LUCA
ZAMPELLA, GIUSEPPE
Publication Year :
2011

Abstract

Experimental and computational experiments show that the electrophile MeS+ attacks a single Fe center in Fe-2(propanedithiolate)(CO)(4)(PMe3)(2) followed by isomerization of this terminal thiolato complex to the corresponding mu-SMe derivative

Details

Database :
OAIster
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1308903318
Document Type :
Electronic Resource