An abrasive-free chemical polishing method assisted by nickel catalyst generated by in situ electrochemical plating

Daisetsu Toh, Pho Van Bui, Ai Isohashi, Satoshi Matsuyama, Kazuto Yamauchi, and Yasuhisa Sano, "An abrasive-free chemical polishing method assisted by nickel catalyst generated by in situ electrochemical plating", Review of Scientific Instruments 91, 045108 (2020), https://doi.org/10.1063/1.5141381.
An abrasive-free polishing method using water and a Pt catalyst, called catalyst-referred etching (CARE), has been developed for the finishing of optical and semiconductor surfaces. This method realizes well-ordered surfaces with a smoothness of several tens of picometers without crystallographic disturbance. In this study, we propose a new CARE method using a Ni catalyst with in situ electrochemical plating and dissolution, which enable enhancing the catalytic capability of Ni. This method has advantages to realize more than ten times higher removal rate and better stability compared with the conventional CARE method.