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A Photochemoenzymatic Hunsdiecker-Borodin-Type Halodecarboxylation of Ferulic Acid

Authors :
Zippilli, C. (author)
Bartolome, Miguel Jimenez (author)
Hilberath, T. (author)
Botta, Lorenzo (author)
Hollmann, F. (author)
Saladino, Raffaele (author)
Zippilli, C. (author)
Bartolome, Miguel Jimenez (author)
Hilberath, T. (author)
Botta, Lorenzo (author)
Hollmann, F. (author)
Saladino, Raffaele (author)
Publication Year :
2022

Abstract

A photochemoenzymatic halodecarboxylation of ferulic acid was achieved using vanadate-dependent chloroperoxidase as (bio)catalyst and oxygen and organic solvent as sole stoichiometric reagents in a biphasic system. Performance and selectivity were improved through a phase transfer catalyst, reaching a turnover number of 660.000 for the enzyme.<br />BT/Biocatalysis

Details

Database :
OAIster
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1357880155
Document Type :
Electronic Resource
Full Text :
https://doi.org/10.1002.cbic.202200367