Small-scale physical and chemical structure of diffuse and translucent molecular clouds along the line of sight to Sgr B2

Context. The diffuse and translucent molecular clouds traced in absorption along the line of sight to strong background sources have so far been investigated mainly in the spectral domain because of limited angular resolution or small sizes of the background sources. Aims. We aim to resolve and investigate the spatial structure of molecular clouds traced by several molecules detected in absorption along the line of sight to Sgr B2(N). Methods. We have used spectral line data from the EMoCA survey performed with the Atacama Large Millimeter/submillimeter Array (ALMA), taking advantage of its high sensitivity and angular resolution. The velocity structure across the field of view is investigated by automatically fitting synthetic spectra to the detected absorption features, which allows us to decompose them into individual clouds located in the Galactic centre (GC) region and in spiral arms along the line of sight. We compute opacity maps for all detected molecules. We investigated the spatial and kinematical structure of the individual clouds with statistical methods and perform a principal component analysis to search for correlations between the detected molecules. To investigate the nature of the molecular clouds along the line of sight to Sgr B2, we also used archival Mopra data. Results. We identify, on the basis of c-C3H2, 15 main velocity components along the line of sight to Sgr B2(N) and several components associated with the envelope of Sgr B2 itself. The c-C3H2 column densities reveal two categories of clouds. Clouds in Category I (3 kpc arm, 4 kpc arm, and some GC clouds) have smaller c-C3H2 column densities, smaller linewidths, and smaller widths of their column density PDFs than clouds in Category II (Scutum arm, Sgr arm, and other GC clouds). We derive opacity maps for the following molecules: c-C3H2, (HCO+)-C-13, (CO)-C-13, HNC and its isotopologue (HNC)-C-13, (HCN)-N-15, CS and its isotopologues (CS)-S-34 and (CS)-C-13, SiO, SO, and CH3OH. These maps