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On-surface synthesis of metal–organic frameworks: the critical role of the reaction conditions

Authors :
Comunidad de Madrid
Ministerio de Ciencia e Innovación (España)
Ministerio de Economía y Competitividad (España)
Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas (España)
Sánchez-Sánchez, Carlos [0000-0001-8644-3766]
Martínez, José I. [0000-0002-2086-8603]
Serrate Donoso, David [0000-0002-3260-9641]
Vedini, Alberto [0000-0001-8880-2080]
Jacobson, Peter [0000-0002-5363-3763]
Grill, Leonhard [0000-0002-9247-6502]
Martín-Gago, José A. [0000-0003-2663-491X]
López, María Francisca [0000-0001-7894-566X]
Ruiz del Árbol, Nerea
Sánchez-Sánchez, Carlos
Martínez, José I.
Rodríguez, Luis
Serrate Donoso, David
Verdini, Alberto
Floreano, Luca
Jacobson, Peter
Grill, Leonhard
Martín-Gago, José A.
López, María Francisca
Comunidad de Madrid
Ministerio de Ciencia e Innovación (España)
Ministerio de Economía y Competitividad (España)
Agencia Estatal de Investigación (España)
Consejo Superior de Investigaciones Científicas (España)
Sánchez-Sánchez, Carlos [0000-0001-8644-3766]
Martínez, José I. [0000-0002-2086-8603]
Serrate Donoso, David [0000-0002-3260-9641]
Vedini, Alberto [0000-0001-8880-2080]
Jacobson, Peter [0000-0002-5363-3763]
Grill, Leonhard [0000-0002-9247-6502]
Martín-Gago, José A. [0000-0003-2663-491X]
López, María Francisca [0000-0001-7894-566X]
Ruiz del Árbol, Nerea
Sánchez-Sánchez, Carlos
Martínez, José I.
Rodríguez, Luis
Serrate Donoso, David
Verdini, Alberto
Floreano, Luca
Jacobson, Peter
Grill, Leonhard
Martín-Gago, José A.
López, María Francisca
Publication Year :
2023

Abstract

[EN] Two different metal–organic frameworks with either a honeycomb or Kagome structure were grown on Cu(111) using para-aminophenol molecules and native surface adatoms. Although both frameworks are made up from the same chemical species, they are structurally differ- ent emphasizing the critical role being played by the reaction condi- tions during their growth. This work highlights the importance of the balance between thermodynamics and kinetics in the final structure of surface-supported metal–organic networks.

Details

Database :
OAIster
Notes :
English
Publication Type :
Electronic Resource
Accession number :
edsoai.on1373160239
Document Type :
Electronic Resource