Diffusion induced Li isotopic fractionation during the cooling of magmatic rocks: The case of pyroxene phenocrysts from nakhlite meteorites

Ion-microprobe was used to measure Li abundances and isotopic compositions in pyroxenes from three Martian meteorites belonging to the nakhlite family. The profiles performed across augite crystals from Northwest Africa 817 show a large isotopic zoning from crystal cores (delta Li-7 similar to 0 parts per thousand) to rims (delta Li-7 similar to +20 parts per thousand) while Li abundances are almost constant (similar to 9.2 mu g/g). Unlike NWA 817, the pyroxene studied in the Miller Range 03346 nakhlite shows a zoning in Li abundance, with concentrations increasing from similar to 2.5 mu g/g in the core to similar to 9 mu g/ g in the rim. The augite rim (delta Li-7 = +7 parts per thousand) is slightly enriched in Li-7 with regard to the core (delta Li-7 = +4 parts per thousand), but most of the isotopic variations observed occur at an intermediate position along the profile, where 67 Li falls down to similar to-11 parts per thousand. In the case of Nakhla, Li concentrations in augite increase from cores (similar to 3.5 mu g/g) to rims (similar to 6.5 mu g/g), while the delta Li-7 variation is restricted (i.e., between delta Li-7 = +6.0 and +12.6 parts per thousand). For the three meteorites the Li abundances were also measured in the groundmass, which was found to be enriched in lithium (similar to 10 mu g/g). Conventional magmatic and post-magmatic processes such as alteration and fractional crystallization, fail to explain the dataset obtained on nakhlites. Degassing processes, which were previously proposed to explain the Li distribution in shergottite crystals, cannot result in the strong decoupling between Li abundances and isotopic composition observed in nakhlites. We suggest that the original magmatic Li distributions (concentrations and isotopic compositions) in nakhtites have been modified by diffusion of Li from the Li-rich groundmass towards the pyroxene crystals during sub-solidus cooling. Diffusion appears to have been efficient for NWA 817 and MIL 033