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Gold(I)-Catalyzed 1,6-Enyne Single-Cleavage Rearrangements: The Complete Picture
- Source :
- Acs Organic And Inorganic Au; 10.1021/acsorginorgau.3c00028; Acs Organic And Inorganic Au. 3 (5): 312-320
- Publication Year :
- 2023
-
Abstract
- We identify the factors that rule the selectivity insingle-cleavageskeletal rearrangements promoted by gold(I) catalysts. We find thatstereoconvergence is enabled by a rotational equilibrium when electron-richsubstituents are used. The anomalous Z-selectiveskeletal rearrangement is found to be due to electronic factors, whereas endo-selectivity depends on both steric and electronic factors.
Details
- Database :
- OAIster
- Journal :
- Acs Organic And Inorganic Au; 10.1021/acsorginorgau.3c00028; Acs Organic And Inorganic Au. 3 (5): 312-320
- Publication Type :
- Electronic Resource
- Accession number :
- edsoai.on1443596588
- Document Type :
- Electronic Resource