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The reuse of treated municipal sewage (‘biosolids’) on land is an effective method to divert waste away from landfill and to use an alternative, low cost method of fertilisation. While legislation has mainly focused on the control of nutrient and metal application rates to land, other potentially harmful emerging contaminants (ECs) may be present in biosolids. Up to 80% of municipal sewage sludge is reused in agriculture in Ireland, which is currently the highest rate of reuse in Europe. However, unlike other countries, no study has been conducted on the presence of ECs across a range of wastewater treatment plants (WWTPs) in this country. This study evaluated the concentrations of two ECs in sewage sludge, the antimicrobials triclosan (TCS) and triclocarban (TCC), and their presence in surface runoff following land application in controlled rainfall simulation studies. In 16 WWTPs, concentrations of TCS and TCC were 0.61 and 0.08 µg g −1 , which is at the lower end of concentrations measured in other countries. The concentrations in runoff post land application were also mainly below the limits of detection (90 ng L −1 for TCS, 6 ng L −1 for TCC), indicating that runoff is not a significant pathway of entry into the environment. [ABSTRACT FROM AUTHOR]

Defining critical source areas (CSAs) of diffuse pollution in agricultural catchments depends upon the accurate delineation of hydrologically sensitive areas (HSAs) at highest risk of generating surface runoff pathways. In topographically complex landscapes, this delineation is constrained by digital elevation model (DEM) resolution and the influence of microtopographic features. To address this, optimal DEM resolutions and point densities for spatially modelling HSAs were investigated, for onward use in delineating CSAs. The surface runoff framework was modelled using the Topographic Wetness Index (TWI) and maps were derived from 0.25 m LiDAR DEMs (40 bare-earth points m −2 ), resampled 1 m and 2 m LiDAR DEMs, and a radar generated 5 m DEM. Furthermore, the resampled 1 m and 2 m LiDAR DEMs were regenerated with reduced bare-earth point densities (5, 2, 1, 0.5, 0.25 and 0.125 points m −2 ) to analyse effects on elevation accuracy and important microtopographic features. Results were compared to surface runoff field observations in two 10 km 2 agricultural catchments for evaluation. Analysis showed that the accuracy of modelled HSAs using different thresholds (5%, 10% and 15% of the catchment area with the highest TWI values) was much higher using LiDAR data compared to the 5 m DEM (70–100% and 10–84%, respectively). This was attributed to the DEM capturing microtopographic features such as hedgerow banks, roads, tramlines and open agricultural drains, which acted as topographic barriers or channels that diverted runoff away from the hillslope scale flow direction. Furthermore, the identification of ‘breakthrough’ and ‘delivery’ points along runoff pathways where runoff and mobilised pollutants could be potentially transported between fields or delivered to the drainage channel network was much higher using LiDAR data compared to the 5 m DEM (75–100% and 0–100%, respectively). Optimal DEM resolutions of 1–2 m were identified for modelling HSAs, which balanced the need for microtopographic detail as well as surface generalisations required to model the natural hillslope scale movement of flow. Little loss of vertical accuracy was observed in 1–2 m LiDAR DEMs with reduced bare-earth point densities of 2–5 points m −2 , even at hedgerows. Further improvements in HSA models could be achieved if soil hydrological properties and the effects of flow sinks (filtered out in TWI models) on hydrological connectivity are also considered. [ABSTRACT FROM AUTHOR]

Carbon (C) losses from agricultural soils to surface waters can migrate through water treatment plants and result in the formation of disinfection by-products, which are potentially harmful to human health. This study aimed to quantify total organic carbon (TOC) and total inorganic C losses in runoff after application of dairy slurry, pig slurry, or milk house wash water (MWW) to land and to mitigate these losses through coamendment of the slurries with zeolite (2.36-3.35 mm clinoptilolite) and liquid polyaluminum chloride (PAC) (10% Al2O3) for dairy and pig slurries or liquid aluminum sulfate (alum) (8% Al2O3) for MWW. Four treatments under repeated 30-min simulated rainfall events (9.6 mm h-1) were examined in a laboratory study using grassed soil runoff boxes (0.225 m wide, 1 m long; 10% slope): control soil, unamended slurries, PAC-amended dairy and pig slurries (13.3 and 11.7 kg t-1, respectively), alum-amended MWW (3.2 kg t-1), combined zeolite and PAC-amended dairy (160 and 13.3 kg t-1 zeolite and PAC, respectively) and pig slurries (158 and 11.7 kg t-1 zeolite and PAC, respectively), and combined zeolite and alumamended MWW (72 and 3.2 kg t-1 zeolite and alum, respectively). The unamended and amended slurries were applied at net rates of 31, 34, and 50 t ha-1 for pig and dairy slurries and MWW, respectively. Significant reductions of TOC in runoff compared with unamended slurries were measured for PACamended dairy and pig slurries (52 and 56%, respectively) but not for alum-amended MWW. Dual zeolite and alum-amended MWW significantly reduced TOC in runoff compared with alum amendment only. We conclude that use of PAC-amended dairy and pig slurries and dual zeolite and alum-amended MWW, although effective, may not be economically viable to reduce TOC losses from organic slurries given the relatively low amounts of TOC measured in runoff from unamended slurries compared with the amounts applied. [ABSTRACT FROM AUTHOR]

The uptake and accumulation of metals in plants is a potential pathway for the transfer of environmental contaminants in the food chain, and poses potential health and environmental risks. In light of increased population growth and urbanisation, the safe disposal of sewage sludge, which can contain significant levels of toxic contaminants, remains an environmental challenge globally. The aims of this experiment were to apply municipal sludge, having undergone treatment by thermal drying, anaerobic digestion, and lime stabilisation, to permanent grassland in order to assess the bioaccumulation of metals (B, Al, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, As, Nb, Mo, Sb, Ba, W, Pb, Fe, Cd) by perennial ryegrass over a period of up to 18 weeks after application. The legislation currently prohibits use of grassland for fodder or grazing for at least three weeks after application of treated sewage sludge (biosolids). Five treatments were used: thermally dried (TD), anaerobically digested (AD) and lime stabilised (LS) sludge all from one wastewater treatment plant (WWTP), AD sludge from another WWTP, and a study control (grassland only, without application of biosolids). In general, there was no significant difference in metal content of the ryegrass between micro-plots that received treated municipal sludge and the control over the study duration. The metal content of the ryegrass was below the levels at which phytotoxicity occurs and below the maximum levels specified for animal feeds. [ABSTRACT FROM AUTHOR]

Globally, there is growing demand for increased agricultural outputs. At the same time, the agricultural industry is expected to meet increasingly stringent environmental targets. Thus, there is an urgent pressure on the soil resource to deliver multiple functions simultaneously. The Functional Land Management framework ( Schulte et al., 2014 ) is a conceptual tool designed to support policy making to manage soil functions to meet these multiple demands. This paper provides a first example of a practical application of the Functional Land Management concept relevant to policy stakeholders. In this study we examine the trade-offs, between the soil functions ‘primary productivity’ and ‘carbon cycling and storage’, in response to the intervention of land drainage systems applied to ‘imperfectly’ and ‘poorly’ draining managed grasslands in Ireland. These trade-offs are explored as a function of the nominal price of ‘Certified Emission Reductions’ or ‘carbon credits’. Also, these trade-offs are characterised spatially using ArcGIS to account for spatial variability in the supply of soil functions. To manage soil functions, it is essential to understand how individual soil functions are prioritised by those that are responsible for the supply of soil functions – generally farmers and foresters, and those who frame demand for soil functions – policy makers. Here, in relation to these two soil functions, a gap exists in relation to this prioritisation between these two stakeholder groups. Currently, the prioritisation and incentivisation of these competing soil functions is primarily a function of CO 2 price. At current CO 2 prices, the agronomic benefits outweigh the monetised environmental costs. The value of CO 2 loss would only exceed productivity gains at either higher CO 2 prices or at a reduced discount period rate. Finally, this study shows large geographic variation in the environmental cost: agronomic benefit ratio. Therein, the Functional Land Management framework can support the development of policies that are more tailored to contrasting biophysical environments and are therefore more effective than ‘blanket approaches’ allowing more specific and effective prioritisation of contrasting soil functions. [ABSTRACT FROM AUTHOR]

Diffuse pollutant losses containing phosphorus (P), nitrogen (N), and suspended solids (SS) can occur when agricultural wastes are applied to soil. This study aimed to mitigate P, N, and SS losses in runoff from grassed soils, onto which three types of agricultural wastes (dairy slurry, pig slurry, and dairy-soiled water [DSW]), were applied by combining amendments of either zeolite and polyaluminum chloride (PAC) with dairy and pig slurries or zeolite and alum with DSW. Four treatments were investigated in rainfall simulation studies: (i) control soil, (ii) agricultural wastes, (iii) dairy and pig slurries amended with PAC and DSW amended with alum, and (iv) dairy and pig slurries amended with zeolite and PAC and DSW amended with zeolite and alum. Our data showed that combined amendments of zeolite and PAC applied to dairy and pig slurries reduced total P (TP) in runoff by 87 and 81%, respectively, compared with unamended slurries. A combined amendment of zeolite and alum applied to DSW reduced TP in runoff by 50% compared with unamended DSW. The corresponding reductions in total N (TN) were 56% for dairy slurry and 45% for both pig slurry and DSW. Use of combined amendments reduced SS in runoff by 73 and 44% for dairy and pig slurries and 25% for DSW compared with unamended controls, but these results were not significantly different from those using chemical amendments only. The findings of this study are that combined amendments of zeolite and either PAC or alum reduce TP and TN losses in runoff to a greater extent than the use of single PAC or alum amendments and are most effective when used with dairy slurry and pig slurry but less effective when used with DSW. [ABSTRACT FROM AUTHOR]

In Ireland, Food Harvest 2020 focuses on increasing productivity while enhancing environmental sustainability of agricultural land. On underutilised or marginal land, drainage systems may be installed to expand agricultural enterprises. Mixed nutrient losses are inevitable from any drainage system, but assessing processes leading to differences in nutrient speciation, fractionation and losses in grasslands between locations or flow paths is important to achieve sustainability. This study investigates these processes in overland flow and subsurface drains over three rainfall events from four non-grazed plots recently converted from marginal land in the south-east of Ireland. A shallower water table and smaller plot size resulted in greater water and nutrient losses in overland flow per unit of land area. Nutrient losses were less in subsurface drains. Dissolved organic nitrogen (DON) dominated, but dissolved inorganic nitrogen (DIN) was more abundant in the drains. Particulate phosphorus generally dominated in drains, except in plots with a shallow water table where dissolved unreactive phosphorus (DUP) was more abundant. In overland flow, a shallower water table resulted in a switch from dissolved reactive phosphorus (DRP) to DUP. Fertilisation increased phosphorus losses in overland flow, with DRP dominating. These results highlight the importance of an integrated assessment of the controls on flow and nutrient losses to design drainage systems in marginal lands. [ABSTRACT FROM AUTHOR]

The article presents a study on the state of research and regulatory regime of diffuse phosphorus (P) and sediment loss for tillage soils. It states that soils with high phosphorus content due to fertilizer overuse have been identified as a landscape threat which impacts water quality. It recommends the use of a multiscaled approach involving a catchment and field-scale monitoring coupled with laboratory and small-plot scale rainfall simulation to identify critical areas.

Abstract: Depletion of plant-available soil phosphorus (P) from excessive to agronomically optimum levels is a measure being implemented in Ireland to reduce the risk of diffuse P transfer from land to water. Within the Nitrates and Water Framework Directive regulations the policy tool is designed to help achieve good status by 2015 in water bodies at risk from eutrophication. To guide expectation, this study used soil plot data from eight common soil associations to develop a model of Soil Test P (STP) (Morgan''s extract) decline following periods of zero P amendment. This was used to predict the time required to move from excessive (Index 4) to the upper boundary of the optimum (Index 3) soil P concentration range. The relative P balance (P balance : Total soil P) best described an exponential decline (R 2 =63%) of STP according to a backwards step-wise regression of a range of soil parameters. Using annual field P balance scenarios (−30kgPha−1, −15kgPha−1, −7kgPha−1), average time to the optimum soil P boundary condition was estimated from a range of realistic Total P and STP starting points. For worst case scenarios of high Total P and STP starting points, average time to the boundary was estimated at 7–15 years depending on the field P balance. However, uncertainty analysis of the regression parameter showed that variation can be from 3 to >20 years. Combined with variation in how soil P source changes translate to resulting P delivery to water bodies, water policy regulators are advised to note this inherent uncertainty from P source to receptor with regard to expectations of Water Framework Directive water quality targets and deadlines. [Copyright &y& Elsevier]

The article presents a study on the comparison of the nutrient and sediment releases of five Irish tillage soils. It says that phosphorus loss is an important pathway in agro-environments in which dissolved reactive phosphorus (DRP) is available for biological uptake that poses threat for algal growth. The study was made for the quantification of DRP, particulate phosphorus (PP), and total phosphorus (TP) released in surface runoff which account for fertilizer usage of tillage crops. An analysis of the soil test phosphorus (STP) of Irish tillage soils through the relationship of STP and DTP is made. The results indicate the possibility of producing surface runoff phosphorus concentration by tillage soils.

The article discusses the potential for ochre to sequester phosphorus in an environmentally sustainable fashion. Ochre deriving from coal mine drainage sites in the United Kingdom displays a high phosphorus retention capacity without highly mobilizing metals, indicating that it can potentially adsorb phosphorus from agricultural wastewaters and be used as a fertilizer. A study focused upon untreated acid mine drainage from an abandoned copper-sulfur mine in a catchment of southeast Ireland. Ochre was mixed with phosphorus-amended water in batch experiments and a maximum adsorption capacity was calculated from the Langmuir equation.

The article presents a study on the impact of agriculture on the environment in Ireland. Agriculture in Ireland involves about 270,000 people, 6.191 million cattle, 1.678 million pigs, 4.257 million sheep and 10.7 million poultry. Emerging technologies in Ireland for waste-water treatment include continuously moving biofilm reactors, activated sludge systems, rotating biological contractors, and fluidised-bed biofilm reactors. Legislation in the country reportedly focused on preventing nutrient losses from agricultural sources.