1. Electrochemical Quantification of Dopamine Sensing in Human Samples Using Bromine Doped Layered gC3N4 Nanosheets.
- Author
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Vasu, Dhanapal, Ravi, Pavithra V., Subramaniyam, Vinodhini, Pichumani, Moorthi, Yu-Feng You, and Te-Wei Chiu
- Subjects
BROMINE ,NANOSTRUCTURED materials ,DOPAMINE ,CARBON electrodes ,ELECTROCHEMICAL analysis ,BRASSINOSTEROIDS - Abstract
The halogen, bromine (Br) doped layered graphitic carbon nitride (gCN) nanosheets are constructed for a novel electrochemical detection of dopamine (DA). The Br is successfully immobilized in the gCN host lattice, in which Br provides an N-vacancy for -C-N bonding to improve electron transfer and enhance its electrocatalytic properties. The prepared nanosheets are studied by various analytical analyses and the electrochemical behavior of the designed electrode is studied using cyclic voltammetry (CV). The Br-gCN decorated screen-printed carbon electrode (SPCE) has superior electrochemical activity and is stable during exposure to varied pH, however, exhibited better catalytic activity at pH 7. The Br-gCN/SPEC electrodes and their high electrocatalytic performance are used for the detection of dopamine with a lower limit of detection (LoD) of 5 nM concentration. The Br-gCN decorated electrodes exhibited satisfactory results for cyclic stability (up to 100th cycle), repeatability (up to 6 cycles), reproducibility of similarly constructed 6 electrodes, and their electrochemical performance. Furthermore, the fabricated sensor also exhibited a better recovery (>80%) for real-time urine sample analyses. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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