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Your search keyword '"Serebryanskaya, Tatiyana V."' showing total 2 results
Start Over Author "Serebryanskaya, Tatiyana V." Journal acta crystallographica: section c (wiley-blackwell)
2 results on '"Serebryanskaya, Tatiyana V."'

1. Bis(1-methyl-1 H-tetra­zol-5-yl)diazene and two its copper(I) chloride complexes poly[[[μ-1,2-bis­(1-methyl-1 H-tetra­zol-5-yl)diazene-κ4 N′, N4: N, N4′]dicopper(I)]-di-μ-chloro] and catena-poly[[chloro­copper(I)]-μ-1,2-bis­(1-methyl-1 H-tetra­zol-5-yl)diazene-κ4 N′, N4: N, N4′]

Author

Lyakhov, Alexander S., Serebryanskaya, Tatiyana V., Gaponik, Pavel N., Voitekhovich, Sergei V., and Ivashkevich, Ludmila S.

Subjects
*CRYSTALLOGRAPHY, *COMPLEX compounds, *LIGANDS (Chemistry), *CHEMICAL processes, *POLYMERS, *ATOMS
Abstract

While bis(1-methyl-1 H-tetra­zol-5-yl)diazene, C4H6N10, (I), has no crystallographically imposed symmetry, in the two title chloro­copper(I) complexes, [Cu2Cl2(C4H6N10)] n, (II), and [CuCl(C4H6N10)] n, (III), the organic ligands lie across centres of inversion; in (III), the Cu and Cl atoms additionally lie about a twofold rotation axis in the space group P2/ c. Complex (II) forms a two-dimensional coordination polymer containing tetra­hedrally coordinated CuI atoms, and complex (III) forms a one-dimensional coordination polymer containing five-coordinate square-pyramidal CuI atoms. [ABSTRACT FROM AUTHOR]

Published
2006
Full Text
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2. Bis(1-methyl-1 H-tetra­zol-5-yl)diazene and two its copper(I) chloride complexes poly[[[μ-1,2-bis­(1-methyl-1 H-tetra­zol-5-yl)diazene-κ4 N′, N4: N, N4′]dicopper(I)]-di-μ-chloro] and catena-poly[[chloro­copper(I)]-μ-1,2-bis­(1-methyl-1 H-tetra­zol-5-yl)diazene-κ4 N′, N4: N, N4′]

Author

Lyakhov, Alexander S., Serebryanskaya, Tatiyana V., Gaponik, Pavel N., Voitekhovich, Sergei V., and Ivashkevich, Ludmila S.

Subjects
CRYSTALLOGRAPHY, COMPLEX compounds, LIGANDS (Chemistry), CHEMICAL processes, POLYMERS, ATOMS
Abstract

While bis(1-methyl-1 H-tetra­zol-5-yl)diazene, C4H6N10, (I), has no crystallographically imposed symmetry, in the two title chloro­copper(I) complexes, [Cu2Cl2(C4H6N10)] n, (II), and [CuCl(C4H6N10)] n, (III), the organic ligands lie across centres of inversion; in (III), the Cu and Cl atoms additionally lie about a twofold rotation axis in the space group P2/ c. Complex (II) forms a two-dimensional coordination polymer containing tetra­hedrally coordinated CuI atoms, and complex (III) forms a one-dimensional coordination polymer containing five-coordinate square-pyramidal CuI atoms. [ABSTRACT FROM AUTHOR]

Published
2006
Full Text
View/download PDF

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